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详细内容:TPV 8281-35MED回TPV 8281-35MED PC韩国LG 1300-03 POM 韩国工程塑料 F30-02 PC德国科思创(拜耳) 2605PP沙特1128NK PA66日本三菱工程3010GN30 PC基础创新塑料(西班牙) 9945A NA1A0036 PP马来大腾石化SM-340 PP北欧化工BH975MO TPE荷兰DSMEL530 PBT基础创新塑料357-BK1066 PP韩国乐天化学SB-540 LDPE中石化燕山1F7B PPO 基础创新塑料 646 ABS日本东丽TP10 PC日本三菱工程 GPN2050DF LDPE沙特埃克森美孚LD 650 PBT基础创新塑料WL4540 BK LCP日本宝理E130i-BK210P TPE台湾李长荣1475 LCP日本杜邦3140L-WT010 PPS美国泰科纳6165A6 NC TPE日本三菱化学3705 POM 日本旭化成 5013 PPO 基础创新塑料 HM3020H PA6日本宇部1013NW8 PC日本帝人 ML-3210ZLP GPPS惠州仁信RG-525N PP中石油锦西1102K PBT江苏长春1100-211M TPV 美国埃克森美孚 211-80 HIPS台湾高福HT-50 BK TPV 美国埃克森美孚 703-45PA12 瑞士EMS XE 4116 WH PC/ABS 日本 CK40 PBT惠州南亚1300 TPV 8281-35MED回TPV 8281-35MED TPV 8281-35MED回TPV 8281-35MED HIPS Impact resistant polystyrene (HIPS) is an impact resistant polystyrene product produced by adding polybutadiene rubber particles in polystyrene. introduce 475 is the HIPS machining TPV 8281-35MED回TPV 8281-35MED POM 日本三菱工程 F20-54 PC泰国三菱工程 FIN5000R PA66美国杜邦FR52G45BL TPV 美国AES 9201-65 PP泰国巴塞尔HP544T ABS德国科思创(拜耳)150G22 BK TPU美国路博润UB450 PP韩国乐天化学JM-375 EVA台湾台塑7B60H POM 泰国三菱工程 F20-13 POE泰国陶氏8480 TPV 美国埃克森美孚 8291-85PA PC/ABS 日本 CKF50G20 TPU深圳科思创(拜耳)UT-83A10 PVDF 法国阿科玛 2850 WR PBT马来西亚宝理AN7015B BK PA66上海罗地亚A216BLPC韩国三星 EH-1051 WH PA66美国杜邦FR72G25 V0 PBT日本东丽1264GE30N(B) PBT日本宝理CN5330 BK PBT基础创新塑料553-1001PEI 基础创新塑料 2310R PP台湾李长荣7633WS LDPE中石油大庆2426F HDPE中石化茂名TR-168 PVC天津渤天化工MP1000F PA66法国罗地亚C216 POM 日本旭化成 LT804 PA66上海巴斯夫A3WG7 PA6韩国巴斯夫B3GK24 BK00564 POM 韩国可隆 LF301 PP中石化广州F503 UV PBT基础创新塑料2735 BK1066 TPU德国巴斯夫C95A50 TPV 8281-35MED回TPV 8281-35MED TPV 8281-35MED回TPV 8281-35MED The impact resistance of PS can be processed by many traditional molding methods, such as injection molding, structural foam molding, sheet and film extrusion, hot forming and blow molding. HIPS resin absorbs water slowly, so there is no need for drying in general. Sometimes excessive moisture on the surface of the material will be absorbed, which affects the appearance quality of the final product. Under the temperature of 160 F dry 23h can remove excess moisture. The extrusion of thin films, sheets and profiles is the most useful processing method for HIPS. Anti impact polystyrene has a wide range of processing, so it becomes one of the most easily thermoforming resins. Generally, the melting temperature of the resin is 400 - 500 F, and the melt index range of the resin is 1.5 - 4 g/10min. Rotating, series and shuttle type pressure and vacuum thermoforming equipment are often used. HIPS has excellent thermal stability and shear stability. It can be used for a lot of recycled materials without reducing the performance of products, and the amount of recycled material in hot forming can be as high as 60%. TPV 8281-35MED回TPV 8281-35MED ABS韩国LGAF-305 PC韩国LG GN-1008FM PPO 基础创新塑料 PX2922 HIPS台湾台化HP8250 BK PC日本三菱工程 S-3085 PA6德国巴斯夫8253HS PEI 基础创新塑料 2210R PA11 法国阿科玛 BESN P20 NOIR TL PP韩国韩华道达尔BI972 PC台湾奇美 PC -115U PP中石化镇海F3-045 PP北欧化工HF955MO PP韩国韩华道达尔RJ700 PPO 基础创新塑料 N225X LLDPE泰国SCG化工M3804RU(P) PA12 德国赢创德固赛 X7373 TPU韩国SK S-395A PC德国科思创(拜耳) 1095 901510 TPU美国路博润GP85 ABS韩国LGAF312A PBT美国泰科纳3309HR PA46荷兰DSM TE250F8 BK TPV 美国埃克森美孚 9103-54 PC日本帝人 3110G PA66德国巴斯夫BN50G6HS BKPC基础创新塑料(南沙) EXL1414T AS(SAN)韩国锦湖310TR PA66日本杜邦408L NC010 TPEE台湾长春1155XL PA66日本杜邦HTNFR52G35 BK337 MVLDPE(茂金属)新加坡埃克森美孚3518PA PA12 美国杜邦 PA2072 PBT美国杜邦LW685FR PA12 德国赢创德固赛 L1724 HDPE上海赛科HD5502FA TPV 8281-35MED回TPV 8281-35MED TPV 8281-35MED回TPV 8281-35MED Injection molding is the most used processing method next to the extrusion. The injection molding of the resin is usually carried out on a reciprocating screw injection molding machine with a length to diameter ratio of 16:1 to 24:1 and a compression ratio of 2.5/1 - 3.0/1. The processing temperature is 350 - 500 degree F, but for the flame retardant HIPS, the processing temperature must be less than 470 F to prevent the additive from producing degradation reaction. The melt index of the resin processed by injection molding is generally 5 to 15 g/min. The forming method of structural foam plastics is a common process, using chemical and physical foaming agents. Although a variety of HIPS resin are compatible with each other, but before the operation to clean processing equipment, to ensure good product quality, the impact of acrylonitrile with a PS Th ene styrene copolymer (ABS), polyvinyl chloride (PVC), polypropylene (PP), polyethylene (PE), acrylic resin and most other plastics are not compatible, incompatible plastic mixture separation will produce delamination phenomenon in processing equipment, caused great decline of physical properties. application TPV 8281-35MED回TPV 8281-35MED PBT日本东丽BC38G PBT德国朗盛B4225 LDPE中石化上海LF2700 PA12 德国赢创德固赛 1301(粉) EVA泰国石化WV1055 PC/ABS 镇江奇美 PC-365 LCP日本宝理E472i K(Q)胶日本旭化成K865 LDPE中石化燕山HM1-I7.0 PBT台湾长春5630F-105A PPE 日本旭化成 600H PBT美国泰科纳4602ZHR BK PVC韩国韩华KH-10 POM 基础创新塑料 KL-004A PA66日本杜邦77G33HS1L NC010 PVDF 美国苏威 20810-19 PA12 法国阿科玛 MV1401 PA66德国DOMO66VOM TPU德国科思创(拜耳)460 LCP日本油墨LD-130 PA12 日本宇部 3035JU5 TPV 美国埃克森美孚 241-55 LCP日本宝理E140I BK210JP PBT台湾长春4115-104K PC日本帝人 G-3430F BKPC/ABS 上海科思创(拜耳) T65XF TPU台湾拜耳优得UDS-70AU10POM 日本三菱工程 LO-21 PA46荷兰DSM TS250F6D-GY PA66美国杜邦70G30HSLR TPV 美国埃克森美孚 211-87 PA6法国罗地亚C218V30 BK PC德国科思创(拜耳) 2458 POM 日本旭化成 ZLV40 PC日本住友化学 PC X-2502 TPV 8281-35MED回TPV 8281-35MED TPV 8281-35MED回TPV 8281-35MED Impact resistance PS is easily machinability, good performance and low price, so it is used to manufacture products and industrial products of many uses. The main applications are packaging and disposable supplies, instruments, household appliances, toys and entertainment supplies, and construction industries. The largest use of HIPS is to be used as a packaging and disposable material, especially for food packaging and eating tableware. The main applications include the daily packaging container. A cup, a variety of covers, plates, bowls, etc. are used and distributed for the vending machine. Disposable products such as disc, bottle cap, safety razor, pen and so on are also a part of the use of HIPS. PVC carcinogen, which will undoubtedly affect the development of PVC to some extent. However, the residual VCM has been successfully reduced by vehicle and other ways, so that the content of VCM in PVC resin will be less than 10ppm, which will meet the requirement of hygienic grade resin and expand the application scope of PVC. Even the content of VCM in the resin is less than 5ppm, and the residual VCM is very few after processing. It is basically harmless to the human body and can be used as food and medicine packaging and children's toys. Main classification TPV 8281-35MED回TPV 8281-35MED PPS日本油墨FZL-4033 PC日本帝人 DN-3110P AES 日本UMG WH50 PA6T 美国杜邦 HTN53G50LRHF CPE美国陶氏3611EPOM 美国杜邦 100P SBS中石化巴陵YH-791 PP泰国石化2300KPC/ABS 基础创新塑料 LG9000 PA6台湾集盛BTQ80 PA66美国杜邦HTNFE8200 PC新加坡帝人 L-1225ZL100 PBT台湾长春4115-201D PC基础创新塑料(南沙) FXE1414 PP美国巴塞尔5C37F EPDM 美国陶氏 4760P EAA美国杜邦3440(1) TPU台湾ZA906TS PBT广州LGGP2156FM PA6/66德国巴斯夫C3U HDPE福建阿美亚洲HDL5010 PA46日本DSM N2030B TPU德国巴斯夫1154D50 PP日本普瑞曼J702LJ PBT台湾长春8830 PETG 美国伊士曼 EB062 PP惠州中海壳牌EP300M PVDF 美国3M 11008 PEEK 德国巴斯夫 A2000 PE蜡 泰国SCG化工 LP0100F PA66日本旭化成14G50 BK PA66深圳东丽CM3004 PA66美国杜邦73G30HSL-BK EVA美国埃克森美孚UL-8705 PC基础创新塑料(南沙) ML7694 TPV 8281-35MED回TPV 8281-35MED TPV 8281-35MED回TPV 8281-35MED According to the different application range, PVC can be divided into general PVC resin, high degree of polymerization PVC resin and crosslinked PVC resin. The general PVC resin by polymerization of vinyl chloride monomer is formed under the action of initiator; high degree of polymerization of PVC resin is resin in the polymerization of vinyl chloride monomer added to the system, the chain growth polymerization crosslinking agent; PVC resin is added to the resin crosslinking agent containing dienes and polyenes in vinyl chloride monomer polymerization polymerization system. According to the method to distinguish the vinyl chloride monomer, can be divided into electric stone, and imported ethylene (EDC, VCM) monomer method (on the habits of the ethylene monomer and import system called ethylene method). According to polymerization method, PVC can be divided into four main categories: suspension polyvinyl chloride, emulsion polymerization, polyvinyl chloride, bulk polymerization, polyvinyl chloride and solution polyvinyl chloride. Suspension polyvinyl chloride (PVC) is one of the most productive varieties, accounting for about 80% of the total output of PVC. Polyvinyl chloride suspension method is divided into six models according to absolute viscosity: XS-1, XS-2... XS-6; XJ-1, XJ-2... XJ-6. The meaning of each letter in the model: X- suspension; S- loose type; J- compact. method TPV 8281-35MED回TPV 8281-35MED PC基础创新塑料 DCL-4532 PPO 基础创新塑料 SE1GFN3 TPV 美国埃克森美孚 8271-55B100 PC新加坡帝人 L-1225ZL100 PP韩国韩华道达尔HJ400 PVC宜宾天原SG-3(粉) PA66日本旭化成14G15 PMMA 韩国大山MMA VH001 PC美国陶氏 2061-15 TPU美国路博润5714 PBT美国杜邦SK641FR-BK851 POM 日本宝理 YF-5 POM 泰国三菱工程 FU2025 LCP美国泰科纳E130I VC3052PC基础创新塑料(南沙) FXE1414T TPV 美国埃克森美孚 291-75B150 PPS菲利普R4-XT GPPS香港盛禧奥(斯泰隆)666H POM 日本旭化成 LV450 PVDF 日本吴羽 W#8200(粉) AS(SAN)中石油兰州BHF PPS日本出光C-140SG SBS中石化巴陵YH-815 PA66美国杜邦FR70M30 VO PA66法国罗地亚KC-216P1V15 BK PA6日本宇部1015GC6 TPU德国科思创(拜耳)DP2786AHIPS台湾奇美PH-60 POM 韩国可隆 K700 PA66美国杜邦HTN54G35 BK PVDF 日本吴羽 1000 PA66美国杜邦FR50 BK PMMA 台湾高福 300-AR PC基础创新塑料 DC-1003 TPU深圳科思创(拜耳)UT7-90AU10 TPV 8281-35MED回TPV 8281-35MED TPV 8281-35MED回TPV 8281-35MED polyvinyl chloride PVC can be made by substitution reaction of ethylene, chlorine and catalyst. Because of its fire prevention heat effect of PVC is widely used in all walks of life every kind of products: wire skin, skin fiber, shoes, handbags, bags, accessories, signs and billboards, building decoration supplies, furniture, ornaments, rollers, pipes, toys (such as the famous Italy "Rody" jumping horse), curtain, door, auxiliary medical supplies, gloves, some food preservation paper, some fashion etc.. Polymerization method PVC was prepared by free radical addition polymerization. The polymerization methods were mainly divided into suspension polymerization, emulsion polymerization and bulk polymerization, mainly by suspension polymerization, which accounted for about 80% of the total output of PVC. The pure water, liquefied VCM monomer and dispersant were added to the reactor, then initiator and other auxiliaries were added. After heating to a certain temperature, the VCM monomer was polymerized by free radical to form PVC particles. Continuous stirring makes the particle size uniform and makes the generated particles suspended in the water. In addition, the PVC paste resin was produced by micro suspension, and the properties and paste properties of the products were all good. TPV 8281-35MED回TPV 8281-35MED POE美国埃克森美孚8210 ABS日本UMGTM-20 POM 美国泰科纳 UV140LG-BK PPS日本宝理1130MF PPS菲利普R-7-120 BL PA66美国杜邦70G43L POM 德国赫斯特 C27021 BK POM 韩国工程塑料 F30-02 PA66美国泰科纳7020-2 NF2001 ABS台湾奇美PA-765A PC日本出光 URZ2201 ABS日本旭化成SX-300PC基础创新塑料(西班牙) 102X LLDPE科威特EQUATEEFDC-7050 ETFE 日本旭硝子 TL581(粉) PA66基础创新塑料RFL-449 PC韩国LG GP1000M PA66基础创新塑料RC-1008 LDPE惠州中海壳牌2420K PC日本三菱工程 GS2010MLR PA66基础创新塑料RF-7007HS BK PPO 日本三菱工程 GX1100 BK TPE日本JSR1320P PBT漳州长春4115 202F PP台湾福聚366-4 PA6台湾集盛BF140-N2 PP沙特国家石化B45ML PC基础创新塑料 DFL-4014 PP台湾福聚7433 PBT漳州长春4815 POE泰国陶氏8180PA66美国杜邦80G33HSL GPPS新加坡电气化学MD-100-301 PP台湾福聚7633WS AS(SAN)宁波台化NF2200 TPV 8281-35MED回TPV 8281-35MED TPV 8281-35MED回TPV 8281-35MED The monomer droplets are dispersed in the aqueous phase suspension polymerization method, using oil soluble initiator were dissolved in monomer, polymerization reaction in the droplet, the polymerization heat absorbed by the water in time, in order to ensure that these droplets in water were bead dispersed, need to join the suspension the stabilizer, such as gelatin and polyvinyl alcohol, methyl cellulose, hydroxyethyl cellulose, etc.. Most of the initiators are organic peroxide and azo compounds, such as peroxide two, two isopropyl carbonate, peroxide two, bicarbonate, peroxide two, two ethylhexyl ester, azo two isoheptane, azo two isobutadiene and so on. The polymerization is carried out in a polymerizer with a agitator. After polymerization, the monomer material flows into the recovery tank or stripper recycle monomer. Then into the mixing kettle, water washing then centrifuge dehydration, drying and resin finished products. The vinyl chloride monomer should be removed from the resin as much as possible. As the PVC for food packaging, the content of free monomer should be controlled below 1ppm. During polymerization, the temperature and pressure of the polymerization process must be controlled to ensure that the specified molecular weight and molecular weight distribution range are obtained and the detonation is prevented. The particle size and particle size distribution of the resin is controlled by the stirring speed and the selection and dosage of the suspension stabilizer. The quality of resin is characterized by particle size and particle size distribution, molecular weight and molecular weight distribution, apparent density, porosity, fisheye, thermostability, color, impurity content and free mobility of powder. Polymerization reaction
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